Product ID:PROMAR 400 LATEX INTERIOR FINISH BASE Z SEMI-GLOSS B31 W 403
MSDS Date:03/20/1998
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CLCNW

THE SHERWIN-WILLIAMS CO.

101 PROSPECT AVE. N.W.
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 1NE25

SHERWIN-WILLIAMS CO

CLEVELAND, OH 44115 US

Telephone: 216-566-2902

Cage: 1NE25

0.1 MMHG).

CAS: 107-21-1

RTECS: KW2975000

OSHA PEL 50 PPM

ACGIH TLV: C 50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CALCIUM CARBONATE

CAS: 471-34-1

RTECS: FF9335000

OSHA PEL 15 MG/M3(AS DUST)

ACGIH TLV: 10 MG/M3 (AS DUST)

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 (AS DUST)

ACGIH TLV: 10 MG/M3 (AS DUST)

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

WATER

CAS: 7732-18-5

RTECS: ZC0110000

0.1 MMHG).

CAS: 112-34-5

RTECS: KJ9100000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ROUTES OF EXPOSURE: EXPOSURE MAY BE BY
INHALATION AND/OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF
USE. TO MINIMIZE EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE,
VENTILATION, AND PERSONAL PRO TECTIVE EQUIPMENT. ACUTE HEALTH
HAZARDS: IRRITATION OF EYES, SKIN AND UPPER RESPIRATORY SYSTEM. IN
A CONFINED AREA VAPORS IN HIGH CONCENTRATION MAY CAUSE HEADACHE,
NAUSEA OR DIZZINESS. CHRONIC HEALTH HAZARD: ETHYLENE GLYCOL IS
CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH
DEFECTS IN RATS AND MICE AT HIGH DOSES WHEN GIVEN IN DRINKING WATER
OR BY GAVAGE. THERE IS NO EVIDENCE TO IN DICATE IT (EFFECTS OF
OVEREXPOSURE)
Explanation of Carcinogenicity:CARBON BLACK: IARC GROUP 2B, VOLUME 65,
PAGE 149, 1996 . CARBON BLACK IS CLASSIFIED AS POSSIBLY
CARCINOGENIC TO HUMANS (GROUP 2B) BASED ON EXPERIMENTAL ANIMAL
DATA. HOWEVER, THERE IS INSUFFICIEN T EVIDENCE IN HUMANS FOR ITS
CARCINOGENICITY.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT'D):
CAUSES BIRTH DEFECTS IN HUMANS. PROLONGED OVEREXPOSURE TO SOLVENT
INGREDIENTS IN INGREDIENT SECTION MAY CAUSE ADVERSE EFFECTS TO
LIVER AND URINARY SYSTEMS. RATS EXPOSED TO TITANIUM DIOXIDE DUST
AT 250 MG/M3 DEVELOPED LUNG CANCER. HOWEVER, SUCH EXPOSURE LIMITS
ARE NOT ATTAINABLE IN THE WORKPLACE. SIGNS OF OVEREXPOSURE: REDNESS
AND ITCHING OR BURNING SENSA TION MAY INDICATE EYE OR EXCESSIVE
SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:IF INHALED: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. IF ON SKIN: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE USE. IF IN EYES: FLUSH EYES WITH LARGE AMOUNTS
OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SWALLOWED: GET
MEDICAL ATTENTION.

Flash Point:NONE
Lower Limits:N.AP.
Upper Limits:N.AP.
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. (FIRE
FIGHTING PROCEDURE CONT'D) EXPOSED TO EXTREME HEAT.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN
(EXTING MEDIA)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. FLAMMABILITY
CLASSIFICATION: NOT APPLICABLE.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:DOL STORAGE CATEGORY: NOT APPLICABLE.
KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED
CONTAINERS WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE
INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. USE ONLY WITH
ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY (OTHER
PRECAUTIONS)
Other Precautions:HANDLING/STORAGE (CONT'D): MIST. AVOID CONTACT WITH
SKIN AND EYES.

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION
AGAINST MATERIALS IN THE INGREDIENTS SECTION. WHEN SANDING OR
ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR APPROVED BY
NIOSH FOR DUST WHICH MAY BE GENERATED ( HYGIENE PRACT)
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE TO MATERIALS IN INGREDIENTS SECTION IS MAINTAINED BELOW
APPLICABLE (OTHER PROT EQUIP)
Protective Gloves:WEAR IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . VENTILATION (CONT'D): EXPOSURE LIMITS. REFER TO
OSHA STANDARDS 1910.94, 1910.107, 1910.108.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
WASH HANDS AFTER USING. RESPIRATORY PROTECTION (CONT'D): FROM THIS
PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE.
Supplemental Safety and Health
THESE COATINGS MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE
PARTICULATES (LISTED "AS DUST" IN INGREDIENTS SECTION) WHICH MAY
BE PRESENT AT HAZARDOUS LEVELS ONLY DURING SANDING OR ABRADING OF
THE DRIE D FILM. IF NO SPECIFIC DUSTS ARE LISTED IN INGREDIENTS
SECTION, THE APPLICABLE LIMITS FOR NUISANCE DUSTS (OTHER INFO)

Boiling Pt:=100.C, 212.F
B.P. Text:RANGE: 212 - 477F.
Melt/Freeze Pt:M.P/F.P Text:N.A.
Vapor Density:> THAN AIR
Spec Gravity:1.13 - 1.50
pH:9.0 - 9.5
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:N.A.
Appearance and Odor:NOT SPECIFIED BY MANUFACTURER .
Percent Volatiles by Volume:56-80%

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THESE PRODUCTS IS NOT HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED
CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL
REGULATIONS REGARDING POLLUTION.

Toxicological Information:N/P.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:INGREDIENTS SUBJECT OT THE REPORTING
REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
(SARA) SECTION 313, 40 CFR 372.65C: 2-(2-BUTOXYETHOXY)-ETHANOL AND
ETHYLENE GLYCOL.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THESE PRODUCTS ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:THIS PRODUCT CONTAINS CHEMICALS KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE CANCER.